John Delacour: "shellac adheres to the wood (and all sorts of other things) in a very
special way; it becomes a part of the wood. Besides that the
thickness of a french-polished (shellac) finish is far less than what
can normally be achieved with other lacquers."
I have done some French polishing, but when I was comparing shellac with lacquer as a finish, I was thinking of times when I brushed on a couple fairly heavy coats. I have a set of shelves I did that with 30 years ago, and when it gets dinged, the finish dents with the wood, at least considerably more than nitro lacquer (sprayed, about the same thickness) does. With the lacquer, the finish shatters almost without the wood denting. Taking a flake of dried lacquer, similar to one of flaked shellac, it seems more brittle and less "tough."
In any case, with hammers, we are talking about a very, very thin solution, on the order of 5% or less (at least I am using it that thin). If we think of saturating some volume of fibers, when it dries, the volume of solids will be in that same proportion (more or less - %weight and %volume are not all that different). As I picture it (and I would love to see electron micrographs to clear this up), most of the material would coat the fibers. Some might penetrate the interior of fibers, some would collect in joints where fibers cross. So we end up with fibers with a thin coating, making them stiffer. When we insert a needle, this coating either fractures or bends with the fiber. I am guessing it bends a little more with shellac, fractures a little more with lacquer, though I can't be sure.
With respect to rates of evaporation and cure, that is an open question, but with such a thin coating, it will not be as long as with furniture finish, where the solvent has to migrate through hardened outer surfaces. Lacquer can be soft on a piano surface for a good long time (I can remember not too many years ago all the new Steinways I saw had big dents where the lid buttons bore on the rim - obviously they didn't allow enough time for curing). Lacquer thinner has more retardants than solvents, as I understand, designed to make subsequent coats melt the undercoat before drying, and to keep from getting blush due to cold from too rapid evaporation. My guess is that lacquer thinner would evaporate about the same as alcohol, maybe a bit slower. Anyone know for sure?
My take is that the fact a lacquered hammer sounds harder over time has more to do with wear and use than it does with the curing of the material - after an initial week or so. I could be wrong.
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Fred Sturm
fssturm@unm.edu -------------------------------------------