This always helps me keep perspective when considering the daily hazards in my profession.
Original Message:
Sent: 11-07-2024 12:07
From: Peter Grey
Subject: How safe is PTFE powder?
Cindy,
Agreed...always check other viewpoints. I felt that his candor conveyed an honest effort to be accurate.
However we know that we cannot eliminate all toxins from our environment.
Peter Grey Piano Doctor
------------------------------
Peter Grey
Stratham NH
(603) 686-2395
pianodoctor57@gmail.com
Original Message:
Sent: 11-07-2024 09:08
From: Lucinda Strehlow
Subject: How safe is PTFE powder?
Read The China Study with care and also look up research that refutes it.
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Cindy Strehlow, RPT
Urbana, IL
Original Message:
Sent: 11-06-2024 15:55
From: Peter Grey
Subject: How safe is PTFE powder?
Blaine,
This is slightly off topic but interestingly aflatoxin figures prominently in the research of Dr. T. Colin Campbell, PhD in his book "The China Study" in which he discovered a link between diet and the body's ability to effectively cope with this particular carcinogen (and potentially others). Worth a read, if you haven't already.
Peter Grey Piano Doctor
------------------------------
Peter Grey
Stratham NH
(603) 686-2395
pianodoctor57@gmail.com
Original Message:
Sent: 11-06-2024 00:23
From: Blaine Hebert
Subject: How safe is PTFE powder?
Everyone, please remember:
The most powerful carcinogen now known to mankind is aflatoxin:
https://en.wikipedia.org/wiki/Aflatoxin
This is produced by common bread mold and is found in almost every carbohydrate food product we eat today. The fungi grow in soil, decaying vegetation and various staple foodstuffs and commodities such as hay, maize, peanuts, coffee, wheat, millet, sorghum, cassava, rice, chili peppers, cottonseed, tree nuts, sesame seeds, sunflower seeds, and various cereal grains and oil seeds. In short, the relevant fungi grow on almost any crop or food.
Also, the air you breathe is radioactive, as is every food product you eat. This is due to radioactive Cabron 14, produced by gamma rays from space that is incorporated into all of our plants and from them into our animal proteins, as well as the air you breathe.
Perspective is important!
------------------------------
Blaine Hebert RPT
Duarte CA
(626) 390-0512
Original Message:
Sent: 11-05-2024 19:37
From: Norman Brickman
Subject: How safe is PTFE powder?
Blaine, please check again, or contact me off-line. Do a general search on CAS 68424-85-1 and I believe you will find it listed as Benzalkonium Chloride (not Quaternary ammonium cation). Regardless, the important thing, as I understand it, is the American Chemical Society number itself. I could also give you a couple other CAS numbers that are, or have-been, associated with humidifier pad treatment chemicals.
https://www.chemicalbook.com/ChemicalProductProperty_EN_CB1712971.htm
I'll also attach an example here of an SDS (Safety Data Sheet) for the "biocidal product" CAS 68424-85-1. There are other SDS's available on the Web from other manufacturers – with similar warnings to this one.
The Wikipedia site on it is https://en.wikipedia.org/wiki/Benzalkonium_chloride
All: the discussion in this thread is about potential health aspects when humidifier pad treatment (CAS 68424-85-1) is dispersed into the air in minute quantities, NOT about handling of the bottled liquid. When handling the pad treatment liquid, I suggest you FOLLOW any warnings on the bottle.
David, yes, I personally recommend alternatives like room humidification, and whole house humidification. And of course the time tested use of small water cups in or near the piano. My recollection is that the non-evaporative room humidifiers all contain instructions directing a thorough cleaning of the unit every week or two. Flowing water centralized whole house humidifiers are different. Regards, Norman.
------------------------------
Norman Brickman
Potomac Piano Service
Potomac, Maryland
potomacpiano@verizon.net
https://potomacpiano.com
(301) 983.9321
Original Message:
Sent: 11-05-2024 17:59
From: Blaine Hebert
Subject: How safe is PTFE powder?
Norman,
I am still looking into this, but it appears that CAS 68424-85-1 might be this:
https://en.wikipedia.org/wiki/Quaternary_ammonium_cation
Found in hand cleaner and household disinfectants that we use every day.
------------------------------
Blaine Hebert RPT
Duarte CA
(626) 390-0512
Original Message:
Sent: 11-05-2024 16:38
From: Norman Brickman
Subject: How safe is PTFE powder?
Blaine, a little more information for your prep for next year's PTG talk on chemicals and biohazards – as relates to piano humidity systems. One topic to consider is potential electrical hazard. Most grand piano installations do not include a protection cover, so the obvious hazard potential of a mix of water with electricity for young toddlers. But this might be a difficult topic for you if the circuits in use are proprietary.
A little more on humidifier pad treatment chemicals -- I would classify the systems as having a 50% duty cycle year-round since my understanding is that the humidistat relays are likely SPDT (Single Pole Double Throw). Meaning that in the summer, after the humidity is lowered by the dehumidifier section, the heater on the liquid is once again turned on to add water (containing the pad treatment chemical) to the room and increase its humidity. So I figure that for a 24x7x365 operation the air exposure (for CAS 68424-85-1) might be around 2 or 3 ml (milliliters) per day year round.
The SDS (Safety Data Sheet) for CAS 68424-85-1 certainly indicates caution for the chemical, but does not give guidance (that I have found) for breathing in diluted fumes. I tried ChatGPT with "how dangerous is an evaporative heater humidifier with CAS 68424-85-1 chemicals going into the air". A short summary: it is not considered highly toxic, but for sensitive individuals such as those with asthma or respiratory issues it can cause irritation of the respiratory system, eyes, or skin. I assume that this requires a discussion with the piano owner. The size of the room and the amount of personal exposure might be of interest. Regards, Norman.
------------------------------
Norman Brickman
Potomac Piano Service
Potomac, Maryland
potomacpiano@verizon.net
https://potomacpiano.com
(301) 983.9321
Original Message:
Sent: 11-05-2024 12:51
From: Blaine Hebert
Subject: How safe is PTFE powder?
Ron,
Two things that this AI article missed: As piano techs we are in regular (sometimes alarming) contact with lead oxide, the white powder that forms on lead and is much more soluble and absorbant through skin. Old paint is another source of lead contamination, the facility that my workshop is in is an old WWII Navy facility and everything was painted with lead based paint. I was concerned when a painting crew was diligently sanding buildings before repainting, all without protection (but hey, they were the lowest bid).
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Blaine Hebert RPT
Duarte CA
(626) 390-0512
Original Message:
Sent: 11-05-2024 11:46
From: Ron Newman
Subject: How safe is PTFE powder?
Mathias: Would the water based formulation of PTFE work for knuckles, if allowed to dry before use? A quick look at the McLube website and I didn't see anything on it. But I did see that they have
a whole page on transitioning away from PFAS-containing products.
Update:
PFTE:
N95 masks will filter particles down to 0.3 microns. Same for HEPA filters that you might use in your vacuum cleaner. Some say that electrostatic attraction on the sides of the pores will filter down to 0.1 microns in N95 masks. However, PTFE for lubricant use can have particles less than 0.1 micron, although larger particle sizes are also used. Anyone know the specifics of the PTFE powder we use in piano work?
Sources:
PVC-E glue:
If anyone has any information on these, please let us know.
Lead weights:
To save search time, I just used ChatGPT to summarize. Would be happy to hear if anyone has information that contradicts this.
Prompt:
How much lead exposure can you get by manually handling lead in its solid state?
Here's what it said:
When handling solid lead (such as lead ingots, lead sheets, or lead-based materials) in a controlled and proper manner, the risk of significant lead exposure is generally low, as long as certain precautions are taken. Lead exposure primarily occurs when lead is ingested, inhaled, or absorbed through the skin, so how you handle it is key.
Here are a few important points about handling lead safely in its solid state:
### 1. **Dust and Particles**
The main risk of lead exposure comes from the generation of lead dust or fumes. Lead in its solid state (such as an ingot or a piece of pipe) is not inherently dangerous unless it is being worked with in a way that produces lead dust, like sanding, cutting, or grinding. These processes can generate tiny particles of lead that can be inhaled or ingested. However, simply handling solid lead without disturbing it is less likely to result in exposure.
### 2. **Skin Contact**
Lead is poorly absorbed through the skin, so handling solid lead in its natural state (not in powder or molten form) does not pose a significant risk of absorption. However, it's still advisable to wash hands thoroughly after handling lead and to avoid eating, drinking, or smoking around lead. Lead dust on the skin, from handling or contact with lead-contaminated tools or surfaces, can be transferred to your mouth or other areas, increasing the risk of exposure.
### 3. **Lead in Molten Form**
The main hazard comes from working with molten lead, as lead fumes are produced when heated. These fumes can be highly toxic when inhaled, even in small amounts. Always use proper ventilation and personal protective equipment (PPE) such as a respirator when working with molten lead.
### 4. **Precautions to Take**
To minimize exposure when working with solid lead, consider the following safety measures:
- Wear gloves to prevent skin contact and reduce the risk of transferring lead to your face or mouth.
- Wash hands thoroughly after handling lead, even if you didn't notice any visible dust or residue.
- Work in a well-ventilated area to prevent any lead dust from accumulating.
- Avoid eating, drinking, or smoking while handling lead or in areas where lead dust may be present.
- Regularly clean work areas to minimize the accumulation of lead dust.
### Conclusion
While handling solid lead without generating dust or fumes poses a low risk of exposure, lead remains a toxic substance, and it's important to handle it with care. The key risks come from lead dust, improper disposal, and exposure through ingestion or improper personal hygiene. If you're just handling solid lead without cutting, grinding, or heating it, the exposure risk is minimal. However, always take safety precautions, such as wearing gloves and washing your hands afterward, to minimize any potential risks.
Original Message:
Sent: 11/4/2024 3:20:00 PM
From: Daniel DeBiasio
Subject: RE: How safe is PTFE powder?
The solvent in McLube 444 was n-propyl bromide. Regulations of which led to it being discontinued.
------------------------------
Daniel DeBiasio
Technical Education & Support
ddebiasio@steinway.com
718-267-3229
Steinway & Sons
Original Message:
Sent: 11-02-2024 14:35
From: Mathias Walters
Subject: How safe is PTFE powder?
The main solvent in McLube 1725L (clear liquid) is heptane, but it also has a small amount of toluene in it. Toluene is one of the ingredients used in lacquer thinner.
I wear an N95 mask whenever I use liquid McLube for any more than a single swab and make sure it's somewhere that won't get spilled.
I'm not sure what all else the propellant mixture has or the contents of the discontinued McLube 444A. McLube has a new formulation, 444 TTG that is non-flammable and also has some water based formulations of both PTFE and MoS2 solutions that I'm eager to test!
------------------------------
Mathias Walters
North Charleston SC
(843) 619-7593
Original Message:
Sent: 11-02-2024 14:16
From: Walter Bagnall
Subject: How safe is PTFE powder?
I quit usng McLube, mainly because I accidentally spilled some and was shocked at what it did to the lacquer finish. Had no idea. Caused me a lot of trouble. Anything that caustic I can do without.
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Walter Bagnall
Chillicothe OH
Original Message:
Sent: 11-02-2024 11:50
From: Ron Newman
Subject: How safe is PTFE powder?
Norman, thanks for the heads up on humidifier additive chemicals. Yes, if anyone has more definitive information on those please let us know.
Lubricants:
I think also of McLube, which was taken off the market for health hazard reasons. So what's in ProLube and CLP? Or Flitz? I haven't checked out the SDS's.
CA:
I personally use the "foam safe", "odorless" versions of CA made by Bob Smith Industries, available from Howard Piano Industries. If you happen to be wearing gloves with nylon mesh backing and spill a drop of CA (whether it was "foam safe", I can't remember) on the back of your hand, it will immediately burn through the glove and into your hand. Ask me how I know. Scary stuff. On the other hand, CA is commonly used in surgery in lieu of stitching. So go figure.
I also carry an actual gas mask for full-piano CA application, though I don't think I have ever used it. Even with the mask on, you can still smell odors. I wonder if that means the mask isn't working? I open the windows and have a fan on. And I wear eye protection, for the fumes more than for droplets.
I'm looking for the balance between paranoia and taking wise precautions.
Original Message:
Sent: 11/2/2024 10:58:00 AM
From: Norman Brickman
Subject: RE: How safe is PTFE powder?
Ron, I have been following the topic of forever chemicals a little but I hadn't thought of the teflon powder that we use as being a contributor. PFAS's are a serious topic – thanks for the heads-up on teflon use.
In September of last year, in my post "Piano Humidifying Systems – Is There A Health Consideration?", I raised a perhaps similar concern -- about the necessary use of a bacterial and mildew control chemical in the water of piano evaporative heating systems for humidity control. (They often contain American Chemical Society CAS #68424-85-1 and/or CAS 7732-18-5 and/or CAS 8030-78-2). As with your ChatGPT search, I also did a couple AI searches on the chemicals (and reading of SDS's) and the results were not very pleasant! So I was worried about the danger to us in servicing pianos as well as to our customers who have them in their home – of breathing minute quantities of the chemicals.
The VERY CLEAR consensus of our colleagues was that humidifier additive chemicals are not a problem, at least in part due to the minute quantities that we and our piano customer's families are breathing in. Comparisons provided included putting chemicals in a toilet bowl, and houses that are full of all sorts of chemicals, and odors from CA glues, and how California over-does warning labels, and lots more! The message is that we all have to put things in perspective.
So bottom line, Ron, is that might similar reasoning also apply to teflon and PFAS's? Still, if anyone has a link to a refereed scientific study showing that inhaling minute quantities of CAS 68424-85-1 is perfectly healthy, I would appreciate them providing it. I could then change one (#1) of the several considerations with piano humidifying systems that I have in my article on the topic on my Web site. Thanks in advance. Regards, Norman.
------------------------------
Norman Brickman
Potomac Piano Service
Potomac, Maryland
potomacpiano@verizon.net
https://potomacpiano.com
(301) 983.9321
Original Message:
Sent: 11-02-2024 00:42
From: Mathias Walters
Subject: How safe is PTFE powder?
I was just looking into this pretty in depth the other day with my partner (PhD in neuroscience and close to completing their MD). There are very few papers published on the health effects of inhaled PTFE powder and there are no literature review articles that we could find. Basically: inconclusive, there's just not enough data yet.
That being said, there is a LOT of research currently being done on the effects of microplastics in general and the gist is that it's not great. Jury is still out on exactly how bad, but any amount is worse than no amount.
Any SDS for PTFE powder usually says to use it only in a well ventilated area or with a mask.
------------------------------
Mathias Walters
North Charleston SC
(843) 619-7593
Original Message:
Sent: 11-01-2024 07:35
From: Ron Newman
Subject: How safe is PTFE powder?
I wondered, since Teflon is one of the primary repositories of PFAS ("forever chemicals"). Rather than doing a Google search, I used ChatGPT to survey lots of documents quickly. Here's the result:
Does PTFE powder contain PFAS chemicals?
"Yes, PTFE (polytetrafluoroethylene) is a type of fluoropolymer and is considered a member of the larger family of PFAS (per- and polyfluoroalkyl substances) chemicals. While PTFE itself is stable and does not break down easily in the environment, some manufacturing processes or additives used in PTFE production might involve other PFAS compounds. It's important to distinguish between the properties of PTFE and the broader category of PFAS, as not all PFAS are the same and their environmental impacts can vary."
Do humans absorb PFAS chemicals through the skin after touching PFTE powder?
"The absorption of PFAS chemicals through the skin is generally considered to be low. PTFE powder itself is not likely to pose significant risks for skin absorption. However, while direct contact with PTFE powder may not lead to significant PFAS absorption, it's essential to be cautious, as some PFAS compounds can be present in other formulations or products.
Long-term exposure or inhalation of fine particles could potentially pose health risks, so using appropriate safety measures, like gloves and masks, is advisable when handling any chemical powders."
More sources on PTFE powder specifically would be welcome.
I got into this search after looking into a report that PFAS chemicals are present in 33% of dental floss. The sources for that are instructive on PFAS in general. Naturally, the ADA and the manufacturers say there's no problem. Here are those sources:
https://www.hsph.harvard.edu/news/hsph-in-the-news/dental-floss-harmful-chemicals/
https://www.health.com/condition/oral-health/pfas-floss
https://www.rdhmag.com/patient-care/article/14233922/pfas-in-dental-floss-bad-for-our-health
https://www.mamavation.com/beauty/toxic-pfas-dental-floss-tooth-floss.html
------------------------------
Ron Newman
Santa Fe NM
(505) 204-8255
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